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The campaign will begin Monday, a day before a number of the group's state leagues are targeting lawmakers locally with demonstrations on climate change.

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According to League spokesman Jeff Gohringer, the television ads will "hold climate change deniers in Congress accountable for their anti-science views and voting records."

Though the ads are backed by the group's advocacy arm, rather than its PAC, it believes targeting climate change skeptics in Congress could be a winning argument in 2014.

Last election cycle, the group launched a $1.5 million effort to defeat what they called the "Flat Earth Five," five lawmakers who were skeptical of climate change science. All but one were defeated.