A number of Democratic Electoral College electors are planning to use their votes to undermine the election process in opposition to President-elect Donald TrumpDonald John TrumpBill Kristol resurfaces video of Pence calling Obama executive action on immigration a 'profound mistake' ACLU says planned national emergency declaration is 'clear abuse of presidential power' O'Rourke says he'd 'absolutely' take down border wall near El Paso if he could MORE, Politico is reporting.

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Some electors are lobbying their Republican counterparts to vote for someone other than Trump in an attempt to deny him the 270 votes required to elect him, according to the news outlet.

They are also contemplating whether to cast their votes for someone other than Hillary ClintonHillary Diane Rodham ClintonO’Rourke heading to Wisconsin amid 2020 speculation The Hill's 12:30 Report — Presented by Kidney Care Partners — Lawmakers scramble as shutdown deadline nears Exclusive: Biden almost certain to enter 2020 race MORE, like Mitt Romney or Gov. John Kasich (R-Ohio).

With at least six electors already vowing to become "faithless," the defection could be the most significant since 1808, when six Democratic-Republican electors refused to vote for James Madison, choosing vice presidential candidate George Clinton instead.

The electors acknowledge that it is unlikely that they will be able to block Trump from gaining office, Politico reported, but they are optimistic that their effort will raise enough questions about the Electoral College to reform or abolish it.

"If it gets into the House, the controversy and the uncertainty that would immediately blow up into a political firestorm in the U.S. would cause enough people — my hope is — to look at the whole concept of the Electoral College," one of the electors told Politico.

It’s unclear how many, if any, Republicans have signed on to the effort.

Twenty-nine states legally require their electors to obey the results of the popular vote in their state.